納濾技術(shù)在飲用水凈化的應(yīng)用
The application of nanofiltration in the purification of drinking water
飲用水的污染問題愈來愈受到人們的關(guān)注，美、歐、日等發(fā)達(dá)國(guó)家都有改善水質(zhì)的計(jì)劃,，如日本的MAC -2 l計(jì)劃和新MAC - 21 計(jì)劃, 將膜技術(shù)作為水凈化的有效手段。歐、美等國(guó)也支持了許多膜法(NF)水凈化試驗(yàn), 效果明顯。地下水或地表水中的污染物質(zhì)主要是分子質(zhì)量為殺蟲劑、除草劑以及因消毒而造成的過量有機(jī)鹵化物, 它們都是有毒甚至是致癌的。納濾膜分離法可去除消毒的副產(chǎn)物、痕量的除草劑、殺蟲劑、重金屬、天然有機(jī)物及部分硬度、SO2 -4 和NO -3 等, 因而是一個(gè)技術(shù)和經(jīng)濟(jì)可行、可望替代傳統(tǒng)活性炭吸附分離法的適宜方法。
The pollution problem of drinking water has been getting more and more attention. The developed countries such as the United States, Europe and Japan have plans to improve the water quality, such as the MAC -2 l program in Japan and the new MAC - 21 plan, and use membrane technology as an effective means of water purification. Many European and American countries have also supported a lot of membrane water purification (NF) tests. Contaminants in groundwater or surface water are mainly molecular mass of pesticides, herbicides, and excessive organic halides caused by disinfection, which are both toxic and even carcinogenic. Nanofiltration membrane separation method can remove the disinfection by-products, trace herbicides, pesticides, heavy metals, natural organic compounds and partial hardness, SO2 -4 and NO -3, so it is a feasible and economical method to replace the traditional activated carbon adsorption separation method.
一般的過程為 :進(jìn)水→預(yù)處理(絮凝、過濾等)→MF(UF)→NF→出水(備用)。其優(yōu)點(diǎn)是水質(zhì)好且穩(wěn)定, 化學(xué)藥劑用量少, 占地少, 節(jié)能, 省勞力,易管理和維修, 基本上可零排放。利用NF膜去除水中農(nóng)藥, 大部分農(nóng)藥的脫除率均可達(dá)到99%以上, 如:阿特拉津(A trazine)、苯他松(Bzntazone)、敵敵畏(D ichlorvcs)、敵草隆(D iuron)等。目前在法國(guó)巴黎市郊的一座產(chǎn)水量達(dá)140000m3 /d的納濾膜生產(chǎn)飲用水的水廠, 已成功運(yùn)轉(zhuǎn)2年多, 其出水完全能滿足歐共體新近頒布的有關(guān)消毒副產(chǎn)物的指標(biāo)要求, 出水有機(jī)碳(TOC )低于0. 2mg /L ～ 0. 3mg /L, 生物穩(wěn)定性好, 能有效地防止輸水管網(wǎng)中細(xì)菌的繁殖。我國(guó)李靈芝等采用納濾膜循環(huán)工藝以污染嚴(yán)重的淮河水為源水進(jìn)行深度處理試驗(yàn),結(jié)果表明, 該工藝可以有效去除水中的NH+4 、N、N 0-2、TOC、致突變物等雜質(zhì), 獲得安全、合格的飲用水。
The general process is: influent to pretreatment (flocculation, filtration, etc.) to MF (UF) to NF to effluent (reserve). Its advantages are good and stable water quality, less chemical dosage, less land occupation, energy saving, labor saving, easy management and maintenance, and basically zero discharge. Using NF membrane to remove pesticides, most of the pesticides can be removed more than 99%, such as Atala Zin (A Trazine), benzuron (Bzntazone), dichlorvos (D ichlorvcs), and diuron (D iuron). At present, a water plant producing drinking water with a water yield of 140000m3 /d in the suburb of Paris, France, has been successfully running for more than 2 years. The effluent completely meets the requirements of the European Community's newly issued index of disinfection by-products. The effluent organic carbon (TOC) is lower than 0. 2mg /L to 0. 3mg /L, and the biological stability is good and can be effectively prevented. The propagation of bacteria in the pipeline network. Li Lingzhi, China, and so on, using the nanofiltration membrane cycle technology to treat the polluted Huaihe water as the source water, the result shows that the technology can effectively remove the impurities such as NH+4, N, N 0-2, TOC, mutageny and so on, and obtain safe and qualified drinking water.